Very few electrochemical cells can be modeled using a single equivalent-circuit element. Instead, EIS models usually consist of a number of elements in a network. Both serial and parallel combinations of elements occur.
Fortunately, there are simple formulas that describe the impedance of circuit elements in both parallel and series combinations.
Impedance of parallel components | Impedance of series components |
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For linear impedance elements in series, calculate the equivalent impedance from:
For linear impedance elements in parallel, calculate the equivalent impedance from:
Here we calculate two examples to illustrate a point about combining circuit elements. Suppose we have a 1 W and a 4 W resistor in series. The impedance of a resistor is the same as its resistance. We thus calculate the total impedance as:
Resistance and impedance both go up when resistors are combined in series.
Now suppose that we connect two 2 mF capacitors in series. The total capacitance of the combined capacitors is 1 mF.
Impedance goes up, but capacitance goes down when capacitors are connected in series. This is a consequence of the inverse relationship between capacitance and impedance.