Solid oxide fuel cell cathodes prepared by infiltration of LaNi0.6Fe0.4O3 and La0.91Sr0.09Ni0.6Fe0.4O3 in porous yttria-stabilized zirconia
By Lee, Shiwoo; Bevilacqua, M.; Fornasiero, P.; Vohs, J.M. & Gorte, R.J.
Published in Journal of Power Sources
2009
Abstract
SOFC composite electrodes of yttria-stabilized zirconia (YSZ) and either LaNi0.6Fe0.4O3 (LNF) or La0.91Sr0.09Ni0.6Fe0.4O3 (LSNF) were prepared by infiltration to a loading of 40 wt% of the perovskite into porous YSZ using aqueous solutions of the nitrate salts. XRD measurements indicated that the perovskite structures were formed following calcination at 850 °C, at which temperature the LNF and LSNF form small particles that coat the YSZ pores. Heating to 1100 °C causes the particles to form a dense film over the YSZ but caused no solid-state reaction. Calcination of an LNF–YSZ composite to 1200 °C led to an expansion of the LNF lattice, suggesting introduction of Zr(IV) into the perovskite; further heating to 1300 °C caused the formation of La2Zr2O7. For 850 °C calcination, the electrode performance of both LNF–YSZ and LSNF–YSZ composites was similar to that reported for composites of YSZ and La0.8Sr0.2FeO3 (LSF), with a current-independent impedance of approximately 0.1 Ω cm2 at 700 °C in air. For 1100 °C calcination, both LNF–YSZ and LSNF–YSZ composites exhibited impedances that decreased strongly under both anodic and cathodic polarization. The implications of these results for preparing electrodes based on LNF and LSNF are discussed.