Engineering oxygen vacancies of cobalt tungstate nanoparticles enable efficient water splitting in alkaline medium
By Luo, Fang; Xu, Ruizhi; Ma, Shuangxiu; Zhang, Quan; Hu, Hao; Qu, Kongang; Xiao, Shenglin; Yang, Zehui; Cai, Weiwei
Published in Applied Catalysis B: Environmental
2019
Abstract
Development of earth-abundant, efficient and stable electrocatalysts for water splitting is of crucial importance for environmentally friendly energy conversion and storage. Here, we report an oxygen deficient cobalt tungstate nanoparticles with diameter of 8 nm (CoWO4-x@C) as efficient bifunctional electrocatalyst for hydrogen evolution reaction (HER) and oxygen reduction reaction (OER), which exhibits comparable HER activity to commercial Pt/C with overpotentials of 32.5 mV and 46.8 mV vs. RHE to deliver current density of 10 mA cm−2 in acidic and alkaline mediums, respectively, ascribed to the rich oxygen vacancies facilitating the hydrogen adsorption and its relative recombination, respectively. Additionally, undetectable degradation is observed for CoWO4-x@C after 10,000 potential cycles indicating high durability. Meanwhile, CoWO4-x@C requires only 295 mV overpotential to deliver 10 mA cm−2 in the OER test, which is better than the benchmarking IrO2 (313 mV). 1.57 V comparably lower than Pt/C-IrO2 (1.59 V) is required for achieving the water splitting current density of 10 mA cm−2 without any degradation for 12 h.