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Nickel doped molybdenum oxide thin film counter electrodes as a low-cost replacement for platinum in dye sensitized solar cells

By Maitra, Soumyajit; Pal, Subhan; Datta, Shyamal; Maitra, Toulik; Dutta, Biswadeep; Roy, Subhasis
Published in Materials Today: Proceedings Materials Today: Proceedings 2020

Abstract

Replacement of expensive platinum counter electrodes has been primarily focusing research on Dye-Sensitized Solar Cells. Here, we present a facile solution-processed thin-film nickel doped molybdenum oxide counter electrode as a cheap alternative of Platinum. The most motivation of doping nickel in molybdenum oxide was to explore the synergic effect produced due to hypo-hyper electronic d orbital coupling between the pair. These results show the shift of valence band energy level upwards to properly align with electrolyte redox potential for facilitating hole transport. We found that optimized 10 mol. % Ni doping yielded the maximum efficiency of the fabricated solar cells.

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