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Characterization and electrochemical assessment of Al-Zn-In alloy with trivalent chromium process coating

By Wang, Xi; Yang, Fan; Viswanathan, Gopal; Wang, Shan-Shan; Frankel, G. S.
Published in Corrosion Science Corrosion Science 2020

Abstract

To reduce self-corrosion of Al-Zn-In pigments in an Al-rich primer, trivalent chromium process (TCP) was applied to the pigments before mixing in the epoxy binder. The formation of TCP and its effects on both the Al-Zn-In bulk alloy and pigment particles were investigated in this study. The TCP layer on the Al-Zn-In alloy has a bilayer structure similar to TCP layers formed on other alloys. The corrosion rate of bulk Al-Zn-In alloy is reduced by the TCP treatment. The TCP layer likely blocks the access of Cl? to the Al-Zn-In alloy, which reduces corrosion attack initiation.

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