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Detailed insight into processes of reversible solid oxide cells and stacks using DRT analysis

By Suboti?, Vanja; K
Published in Energy Conversion and Management Energy Conversion and Management 2020

Abstract

This study demonstrates applicability of the distribution of relaxation times (DRT) methodology to reveal more precise analysis of processes that occur in solid-oxide fuel (SOFC) and electrolysis (SOEC) cells of industrial-size as well as 10-layer stacks. Initially, we show that before starting to interpret the data observed, it is necessary to verify the quality of the impedance data measured in order to be used for further analysis. For the purpose of experimental study, operating parameters were varied and their impact on the system performance was determined. When operating cells and stacks very similar specific frequencies were identified, whereby for the stack one additional peak was observed. In the fuel cell mode the main frequency ranges to link with the processes that occur were identified to be 0.01

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