Anodic oxidation of hydrazine at carbon nanotube powder microelectrode and its detection
By Yuan-Di Zhao,Wei-De Zhang, Hong Chen, Qing-Ming Luo
Published in Talanta
2002
Abstract
Carbon nanotube powder microelectrodes (CNTPMEs) were used to study the anodic oxidation of hydrazine at Carbon nanotube (CNT)--the novel carbon material. It was found that the electrochemical behaviours were greatly improved at CNTs, indicating that the anodic oxidation could be catalyzed at CNTs. The kinetics parameters of this process were calculated, the heterogeneous electron transfer rate constant k was 0.0019 cm s-1, (1-α)nα was 0.22. The CNTPMEs were also found with high sensitivity for hydrazine detection, could be used as hydrazine sensors.