A Stable Homoleptic Divinyl Tetrelene Series
By Roy, Matthew M. D.; Baird, Samuel R.; Dornsiepen, Eike; Paul, Lucas A.; Miao, Linkun; Ferguson, Michael J.; Zhou, Yuqiao; Siewert, Inke; Rivard, Eric
Published in Chemistry – A European Journal
2021
Abstract
Abstract The synthesis of the new bulky vinyllithium reagent (MeIPr=CH)Li, (MeIPr=[(MeCNDipp)2C]; Dipp=2,6-iPr2C6H3) is reported. This vinyllithium precursor was found to act as a general source of the anionic 2σ, 2π-electron donor ligand [MeIPr=CH]−. Furthermore, a high-yielding route to the degradation-resistant SiII precursor MeIPr⋅SiBr2 is presented. The efficacy of (MeIPr=CH)Li in synthesis was demonstrated by the generation of a complete inorganic divinyltetrelene series (MeIPrCH)2E: (E=Si to Pb). (MeIPrCH)2Si: represents the first two-coordinate acyclic silylene not bound by heteroatom donors, with dual electrophilic and nucleophilic character at the SiII center noted. Cyclic voltammetry shows this electron-rich silylene to be a potent reducing agent, rivalling the reducing power of the 19-electron complex cobaltocene (Cp2Co).