Synthesis, structural characterizations, and electrochemical and
By H. Kantekin and G. Sark? and A. Koca and O. Bekircan and A. Akta? and R.Z. Uslu Kobak and M.B. Sa?lam
Published in Journal of Organometallic Chemistry
2015
Abstract
In this study, we report the synthesis and characterization of N-(3-(4-methoxybenzyl)-5-(4-chorophenyl)-4H-1,2,4-triazol-yl)-4-methylbenzenesulfonamide (3) and peripheral functionalized ligand, 1,2-Bis(2-N-(3-(4-methoxybenzyl)-5-(4-chorophenyl)-4H-1,2,4-triazol-yl)-4-methylbenzene sulphonamide)-4,5-dicyanobenzene (4). The reaction of compound 4 with the corresponding metal salts (Zn(CH3COO)2, CoCl2, PbO) in the presence of \DMAE\ with a catalytic amount of 1,8-diazabicyclo[5.4.0]undec-7ene (DBU) gave novel Zn(II) (5), Pb(II) (6) and Co(II) (7) phthalocyanine derivatives. These new metallophthalocyanines (5