Highly-active Pd
By Alexey Serov and Tristan Asset and Monica Padilla and Ivana Matanovic and Ulises Martinez and Aaron Roy and Kateryna Artyushkova and Marian Chatenet and Frederic Maillard and Domnik Bayer and Carsten Cremers and Plamen Atanassov
Published in Applied Catalysis B: Environmental
2016
Abstract
Nanostructured palladium-copper electrocatalysts with Pd:Cu ratios of 1:3, 1:1, and 3:1 were synthesized using a Sacrificial Support Method (SSM) in combination with the thermal reduction of metal precursors. The materials were comprehensively characterized by X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Scanning and Transmission Electron Microscopy (SEM and TEM), surface area measurements (Brunauer-Emmett-Teller, BET) and Differential Electrochemical Mass Spectroscopy (DEMS). The \SSM\ method enables the preparation of nano-sized unsupported Pd-Cu catalysts with uniformly-distributed particles and high surface area, in the range of 40 m2 gcatalyst?1. Their catalytic activity for the electrooxidation of several alcohols (methanol, ethanol, ethylene glycol and glycerol) was investigated in alkaline media. In situ Infrared Reflection Adsorption Spectroscopy (IRRAS) and Density Functional Theory (DFT) calculations were used in order to understand the mechanism of the various alcohols electrooxidation reactions.