Syntheses, structures, and electrochemical studies of N,N?-bis(alkylthiocarbamate)butane-2,3-diimine Cu(II) complexes as pendent alkoxy derivatives of Cu(ATSM)
By Vishnosky, Nicholas S.; Mashuta, Mark S.; Buchanan, Robert M.; Grapperhaus, Craig A.
Published in Inorganica Chimica Acta
2017
Abstract
Abstract A series of N2S2-Cu(II) complexes based on N,N?-bis(alkylthiocarbamate)butane-2,3-diimine ligands have been synthesized and characterized by spectroscopic, electrochemical, and single crystal X-ray diffraction methods. This class of ligands contains a conjugated {N2S2} chelate framework with a non-coordinating, terminal alkoxy (